Nonmetathetic reaction

NHC) ligand, which is generated from a second-generation Grubbs catalyst [Ru] and vinyloxytrimethylsilane and the actual active species for these nonmetathetic reactions, isomerization of a terminal olefin (Scheme 10.6) [15],... 

It should be noted that nonmetathetical enyne reactions to afford 1,3-dienes are known to be catalysed by low-valent transition metals for a recent review see Ref. [96]. 

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