Nonconjugated dienes anodic oxidation

Compared with conjugated dienes, the electrochemistry of nonconjugated dienes is classified into two types, A and B11,12. In type A, the double bond of the diene behaves essentially the same as the double bond of a monoolefin in the anodic oxidation. A typical... [Pg.759]

Despite the fact that the electrochemical oxidation of most of the nonconjugated dienes generally does not give products which result from interaction of the double bonds with one another, the anodic oxidation l-acetoxy-l,6-heptadienes gives intramolecularly cyclized products, that is, the cyclohexenyl ketones (equation 15)13. The cyclization takes place through the electrophilic attack of the cation generated from enol ester moiety to the double bond. [Pg.764]

The anodic oxidation of nonconjugated dienes has been classified into two categories ... [Pg.1167]

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