Non-isothermal, Discontinuous Reaction

Calorimetric investigations under non-isothermal conditions are usually carried out using a discontinuous measurement method. Such a method is concerned with 

For the kinetic analysis of the thermal reaction power q of a reaction running under non-isothermal conditions, the following condition can be used as a base  

A change in temperature does not interfere with the power coefficients vj, only with the rate coefficient k due to the Arrhenius equation 

The relation between the rate of the stoichiometric formula conversion and the enthalpy of the reaction A// , is given by 

For sufficiently small changes in temperature the following can be used as base  

---

Fig. 5.22 Comparison of sensor signal T2f versus time for different rate orders of conversion, triazine A and naphthylamine sulphonic acid B, in aqueous solution, non-isothermal, discontinuous reaction, isoperibolic condition, Ao = Bq...

---