Nitroxyl species metal complexes

Electrophilic attack at coordinated NO may occur at the nitrosyl nitrogen, at the nitrosyl oxygen, or at the metal.96 An example of the first situation is the oxidative addition of acids to electron-rich nitrosyl complexes giving nitroxyl species 112... 

Nitrosyidisulfonic acid, reaction mechanisms, 22 129, 130 Nitrous acid, 33 103 decomposition, rate constants, 22 157 as oxidizing agent, 22 133 reaction mechanisms, 22 143-156 electrophilic nitrosations, 22 144-152 with inorganic species, 22 148, 149 nitrite oxidation by metals, 22 152-154 oxidation by halogens, 22 154, 155 in solution, 22 143, 144 reduction by metals, 22 155, 156 Nitrous oxide reductase, 40 368 Nitroxyl, reaction mechanisms, 22 138 Nitrozation, pentaamminecobalt(III) complexes, 34 181... 

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