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Nitroxyl amide oxide

Figure 4 Bleach oxidation of octan-2-ol using 1 mol% of nitroxyl catalyst (a) PIPO (3.19 mmol/g amine linker)15, ( ) MCM-41 TEMPO (0.60 mmol/g ether linker/2, ( ) Si02 TEMPO (0.87 mmol/g, amine linker/5, ( ) Si02 TEMPO (0.40 mmol/g, amide linker/, ( ) TEMPO... Figure 4 Bleach oxidation of octan-2-ol using 1 mol% of nitroxyl catalyst (a) PIPO (3.19 mmol/g amine linker)15, ( ) MCM-41 TEMPO (0.60 mmol/g ether linker/2, ( ) Si02 TEMPO (0.87 mmol/g, amine linker/5, ( ) Si02 TEMPO (0.40 mmol/g, amide linker/, ( ) TEMPO...
For less reactive 3-imidazoline derivatives containing no iV-oxide oxygen only a nitrosation reaction has been realized, and its results depend on the conditions under which the reaction is conducted. Slow addition of two equivalent amounts of amyl nitrite to nitroxides 13a,b or to 1-hydroxy-4-methyl-3-imidazoline (12a) in liquid ammonia in the presence of sodium amide produces nitroxyl oximes 52a,b. The immediate treatment... [Pg.184]

See other pages where Nitroxyl amide oxide is mentioned: [Pg.382]    [Pg.180]    [Pg.1115]    [Pg.23]    [Pg.411]    [Pg.482]    [Pg.184]   
See also in sourсe #XX -- [ Pg.552 ]



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Amide oxides

Amides oxidation

Nitroxyl

Nitroxylation

Nitroxyls

Oxidative amidation

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