Nitroxy aldehyde

This nitroxyperoxy radical can react with N02 to form a thermally unstable nitroxyperoxynitrate compound react with itself to form a nitrox-yalkoxy radical, hydroxy nitrate, and nitroxy-aldehyde/ketone or react with NO to form a nitroxyalkoxy radical or dinitrate. The nitroxyalkoxy radical can decompose to form an aldehyde/ketone and NOz, or can react with Oz to form a nitroxy aldehyde/ketone. 

Reaction Scheme 7.7 Pathways of the products found in the reaction of isoprene and NO3 for (A) C4-carbonyl, (B) Cs-hydroxy carbonyl, (C) hydroxy nitrate, (D) nitroxy aldehyde, and (E) nitroxy hydroperoxide (Perring et al. 2009)... 

In the experiments with 2-chloro-l-butene and 2-chloro-2-butene, the initial increase in absorption due to nitroxy and nitroperoxy groups were followed by a decrease and by a simultaneous formation of aldehydes and acid chlorides. 

---