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Nitrosyls amido

The amido nitrosyl molybdenum complex MoCI(Tp )(NO)-(NH2)] reacts with alcohols, yielding the bisalkoxo complexes [Mo(OR)2(Tp )(NO)] (R = Me, Et, "Pr, Bu), analyzed by IR and H-NMR spectroscopy.60 Topaloglu and McCleverty also reported the synthesis and characterization of amido- and amido(monoalkylamido)-Mo(Tp )(NO) species61 and of [MoCl-(Tp )(NO)(OC6H4PPh 2-p)].62... [Pg.86]

Nitrosyl, thionitrosyl, azo, hydrazine, hydroxylamine and related ligands Amido ligands... [Pg.2539]

C5 sHfl 6MoN602P2S , Tetraphenylphosphonium nitrosyl(N,N)dimethylcarb-amido)tetrakis(thiocyanato-N)-molybdate(VI), 45B, 907 C56H32Cl2F8N8Rh2 2 H2O, Tetrakis(p-fluorophenyl isocyanide)rhodi-um(l) chloride dimer d-ihydrate, 45B, 908 C56H32CI2N1gOieRh2, Tetrakis(p-nitrophenyl isocyanide)rhodium(I) chloride dimer, 45B, 908... [Pg.412]

CioHi2Cr2N 03, trans-/x-Amido-M-nitrosyl-bis(TT-cyclopentadienyl-nit-rosylchromium), 35B, 543... [Pg.429]

This form of the rate law is similar to that for the nitrosation of amines which is believed to involve a nitrosyl ion attack on the amido nitrogen. A similar mechanism of nitrosyl ion attack on the coordinated hydroxy oxygen would account for the rapid reaction and support the view that the Co—0 bond is not broken. The second-order term in both CNO ] and [H+] can be explained by the formation of N2O3, Eq. (75). The hydroxy complex is produced by the rapid acid-base equilibrium, Eq. (76). [Pg.44]

See other pages where Nitrosyls amido is mentioned: [Pg.104]    [Pg.188]    [Pg.531]    [Pg.830]    [Pg.177]    [Pg.1115]    [Pg.333]    [Pg.94]    [Pg.421]    [Pg.1250]    [Pg.383]    [Pg.494]    [Pg.495]    [Pg.104]    [Pg.2669]    [Pg.3292]    [Pg.94]    [Pg.79]    [Pg.177]    [Pg.203]    [Pg.147]    [Pg.145]    [Pg.21]    [Pg.54]    [Pg.178]    [Pg.660]   
See also in sourсe #XX -- [ Pg.830 ]

See also in sourсe #XX -- [ Pg.3 , Pg.830 ]



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Amido

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