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Nitrosyl fluoride allylic oxidation

Clearly, regio- and chemo-selectivities of this reagent are highly dependent on the substrate structure. Allylic oxidation to give enones has also been reported at the 11-position of steroids upon treatment with nitrosyl fluoride solutions. °°... [Pg.113]

Reductions of the nitrimino-derivative with suitable reagents afforded the ll/ -nitramine, the 11-imine, and the ll/ -amine. Nitrosyl fluoride in ethyl acetate at 50 °C, however, effected allylic oxidation, giving the 9(ll)-en-12-one... [Pg.298]

See other pages where Nitrosyl fluoride allylic oxidation is mentioned: [Pg.314]    [Pg.296]    [Pg.48]    [Pg.176]    [Pg.79]    [Pg.80]    [Pg.210]    [Pg.218]    [Pg.224]    [Pg.225]    [Pg.882]    [Pg.102]   
See also in sourсe #XX -- [ Pg.113 ]

See also in sourсe #XX -- [ Pg.113 ]

See also in sourсe #XX -- [ Pg.7 , Pg.113 ]

See also in sourсe #XX -- [ Pg.7 , Pg.113 ]

See also in sourсe #XX -- [ Pg.113 ]



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Allyl oxide

Allylic fluorides

Allylic oxidation

Fluorides oxidizing

Nitrosyl fluoride

Oxide fluorides

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