Nitrosyl complexes molybdenum dithiocarbamates

A number of other molybdenum(III) nitrosyl complexes have been reported. Addition of dithiocarbamate salt to [MoBr2(CO)4]2 in the presence of o-phenylene-bis(dimethylarsine) (diars) yields, [Mo(CO)(S2CNR2)2(diars)] (R = Me, Et), which in turn are oxidized by [NO]Bp4 to nitrosyls, [Mo(NO)-(S2CNR2)2(diars)]BF4 (Eq. 77) (886). A crystallographic study (R = Et) reveals... 

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