Nitrogen monoxide ruthenium

Other reactions of small inorganic molecules are the oxidation of chloride ion at a Nafion electrode impregnated with a ruthenium 0x0 complex and the reduction of nitrogen monoxide to ammonia at a Co phthalocyanine modified electrode... 

Supported ruthenium carbido-cluster catalysts for the catalytic removal of nitrogen monoxide and sulfur dioxide the preparation process monitored by sulfur K-edge X-ray absorption near-edge structure... 

What is especially intriguing is the reverse behavior exhibited by the use of ruthenium carbonyl as the metal carbonyl. This reaction, which is catalytic in both Ru3(CO)2 and quaternary ammonium halide (which accelerates the rate of formation of the hydride intermediate), occurs in much higher yield under a carbon monoxide than a nitrogen atmosphere (22). The reaction conditions used for the Ru3(CO)12-catalyzed reaction are much milder than those reported using the water gas shift reaction [100°C, 500 psi] (25). 

Ammonia manufacture from lower hydrocarbons, carbon monoxide, steam, and nitrogen in the presence of a ruthenium catalyst. (Shokubai Kasei Kogyo). JP 55047219 A (1980). 

Ruthenium (III) chloride (99.9%), aluminum nitrate (S grade) and benzene (S grade) were obtained from Wako Pure Chemical. Hydrogen was obtained from Nippon Oxygen Co. and used through a dry ice trap. Carbon monoxide (99.5%) was obtained from Takachiho Chemical, and purified by distillation at liquid nitrogen temperature. 

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