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Nitrogen forming three pyramidal bonds

The four sp3 orbitals for these three atoms (i.e. N, O and Cl) form a tetrahedral arrangement having one or more of the hybridised orbitals occupied by a lone pair of electrons. For an isolated atom, nitrogen forms a pyramidal shape where the bond angles are slightly less than 109.5 (c. 107 )fig.(a). This compression of the bond angles is because of the orbital containing the lone... [Pg.40]

Such strong inward pyramidalization of the nitrogens is stabilized by the overlapping of the nitrogen electrons forming a two-center three-electron bond in the cation radi-... [Pg.150]

Finally with nitrogen the bonding of three hydrogen atoms to form NH3, ammonia, takes place through three unpaired p electrons along three mutually perpendicular axes. The molecular structure of ammonia is indeed that of a three-sided pyramid for the same reason as in the water molecule the valency angle is also increased in this case to 105°. [Pg.150]


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Bond-forming

Nitrogen bonds formed

Nitrogen forms

Nitrogen pyramidality

Nitrogen pyramidalization

Pyramidal nitrogens

Pyramidalized nitrogen

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