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Nitrogen-bonded substituents rearrangement reactions

Thereafter, a rearrangement occurs resembling the reactions of carbocations (Sections 8-9B and 15-5E). When the cleavage of the N—O bond occurs, the nitrogen atom would be left with only six valence electrons. However, as the bond breaks, a substituent R on the neighboring carbon moves with its bonding... [Pg.1180]

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Bonding rearrangements

Nitrogen substituents

Substituents reactions

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