Nitrobenzyl nitramine

Nitrobenzyl-2,4,6-trinitro-nitraniline or 2 -Ni-trobenzyl-2,4,6-trinitrophenyl-nitramine, 02N-CgH4.CH2.N(N02).CgH2(w02)3 col eryscs(from alc+acet), mp 149°(with evoln of gas) easily sol in acet or warm AcOH less sol in benz si sol in ale or chlf nearly insol in eth, petr eth or w. 

Nitrobenzyl-2,4,6-trimUo-nitranilinj 4 -Nitro-benzyl-2,4,6-trimtrophenyl-nitramine or Picryl-(4 -nitrobenzyl)-nitr amine nearly col crysts, mp 141 -2° (with evoln of gas) was first prepd by Blank-sma(Ref 2) by heating N-(4-nitrobenzyl)-4-nitro-aniline with nitric acid(d 1.52) and then later by van den Berg(Ref 3), who showed that this compd can also be obtd by nitration of 4 -nitrobenzyl-2 -ni tro aniline, benzyl-2,4-dinitroaniline, benzyl-2, 4,6-trinitroaniline, 4 -nitrobenzyl-2,4-dinitroani-line or 4 -nitrobenzyl-2,4,6-trinitroaniline. 

Dinitro- benzyl-2,4,6- trim trophenyl-nitramine or Picryl-i2,4-dinitrobenzyl)-nitramine, (02N)2 CgH3.CH2.N(N02).CgH2(N02)3 nearly col crysts(from alc+acet), mp 150-1 (with evoln of gas) easily sol in acet moderately sol in warm AcOH diffc sol in ale, benz or chlf insol in eth or petr eth. Can be prepd by nitration of 2 -nitrobenzyl-2,4,6-trinitronitraniiine with abs nitric acid or by nitration of 4 -nitroben2ylaniline (or of benzyi-4-nitroaniline) with mixed nitric -sulfuric acid. Its expl props were not detd Refs i)Beii- not found 2)P.van den Berg,Rec 55,848-9(1936)... 

Nitramine (Tetryl < p-Nitroacetamidoacetophenone p-Nitroacetamidohydroxypropiophenone p-Nitroaminoacetophenone p-Nitrobenzoyl chloride p-Nitrobenzyl bromide p-Nitrobromacetophenone Nitrocellulose Nitrofurazone Nitroglycerin (cu)... 

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