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Nitro-cyclo-propane

Die Ringoffnung von sterisch anspruchsvollen Arylestern der 1-Carboxy-l-nitro-cyclo-propane, vor allem mit weichen C- und Heteroatom-Nukleophilen bietet12 einen poten-tiellen Zugang zu y-substituierten a-Amino-carbonsauren z.B. ... [Pg.538]

Nitro-cyclo-propane CI/C/0-C3H5-NO2 70.6 295.4 Derived from AfH° in ref. 1999BUR... [Pg.408]

Step (Scheme 1.220) [306]. The treatment of nitro compounds with Ag20, DBU, and iodine resulted in bicyclic cyclopropanes 470 and 471 in good yields. The stereoselectivity was generally high. The stereoselectivity depended on the size of the formed ring. The precursors 469 were readily prepared by the conjugate addition of allylic or homoallylic nucleophiles to nitroalkenes. A similar cyclo-propanation has also been reported [307]. [Pg.60]

Propane 3-Nitro-2-(2-oxo-cyclo-hexyl)-l.1.1-lrifluoro- ElOb,. 461 (F,C-CN2- Cll,-NO, + 1-NR2 cyclohexen)... [Pg.666]


See other pages where Nitro-cyclo-propane is mentioned: [Pg.110]    [Pg.110]    [Pg.244]   
See also in sourсe #XX -- [ Pg.110 , Pg.408 ]




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Cyclo-propane

Propane, 1-nitro

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