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Nitriles acylamines

Hydrozirconation. Hydrozirconation of nitriles by Cp2Zr(H)Cl followed by reaction with RCOCl and quenched with nucleophiles gives rise to functionalized amides such as acylaminals and acyl hemiaminals (by adding alcohols and water, respectively). ... [Pg.489]

Am N-Atom unsubstituierte Acylamine ergeben Nitrile (s. S. 1356)6. disubstituierte liefern Carbonsaure-imidium-chloride7. [Pg.629]

Carbonium hexachloroantimonates Modified Ritter reaction Acylamines from alcohols and nitriles... [Pg.394]

SCHEME 9 Acylaminal formation through nitrile hydrozirconation, acylation, and alcohol addition. [Pg.195]

This potentially very useful route to acylaminals was initially tested on simpler substrates, and did prove to be a viable procedure, as shown in Scheme 9. Nitrile 36 was selected as the initial substrate because of our ultimate objective of conducting the procedure on a complex a-alkoxy nitrile psymberin... [Pg.195]

Acylamines from nitriles Extended Bitter reaction... [Pg.93]

See other pages where Nitriles acylamines is mentioned: [Pg.278]    [Pg.51]    [Pg.93]    [Pg.94]    [Pg.96]    [Pg.98]    [Pg.100]    [Pg.102]    [Pg.104]    [Pg.90]    [Pg.358]    [Pg.271]    [Pg.100]    [Pg.187]    [Pg.194]    [Pg.196]    [Pg.203]    [Pg.206]    [Pg.207]   
See also in sourсe #XX -- [ Pg.16 , Pg.59 ]

See also in sourсe #XX -- [ Pg.16 , Pg.59 ]



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