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Nitrido complexes oxidation potentials

Whereas the oxidation state of the rhenium atom is maintained during the reaction of the potentially tetradentate ligand tris(2-diphenylphosphinoethyl)amine, NP3 (179), with the nitrido complex [ReNCl2(PPh3)2], the rhenium(III) complex [ReCl3( 7 -NPP-... [Pg.349]

The electrochemical properties of a number of isostructural osmium(VI)-nitrido complexes, [Os(E)(X)(Y)(Tp )] (Tp = Tp or Tp, E = O, NTol, N X, Y = hydrocarbyl, halide triflate) have been described. It has been reported that the reactivity of these complexes as inner-sphere oxidants does not correlate with their peak reduction potentials, whereas the ease of oxidation of these compounds well parallels their reactivity as oxidants.206... [Pg.169]

Similar current-voltage-potential sweep rate trends were observed for NMnTPP, NMn(o-OCH3)TPP and NMn(p-0CH3)TPP. Table 1 lists the potentials observed for the electrode reactions of the nitrido Mn porphyrin complexes investigated. The increased potential separation between the E1/2 values of the first and second oxidations (as compared to the unhindered porphyrins) reflects the influence of the cap in inhibiting the formation... [Pg.79]

See other pages where Nitrido complexes oxidation potentials is mentioned: [Pg.99]    [Pg.137]    [Pg.735]    [Pg.218]    [Pg.43]    [Pg.235]    [Pg.302]    [Pg.3373]    [Pg.402]    [Pg.402]    [Pg.148]    [Pg.3371]    [Pg.3372]    [Pg.132]    [Pg.174]    [Pg.191]    [Pg.304]    [Pg.1088]    [Pg.1734]    [Pg.42]    [Pg.81]   
See also in sourсe #XX -- [ Pg.302 ]



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Complex potential

Nitrido

Nitrido complexe

Nitrido complexes

Oxidation potential

Oxidizing potential

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