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Nitrides eight-membered ring

The oxidative addition of one equivalent of X2 (X=C1, F) to S4N4 under mild conditions produces 1,5-S4N4X2.106 The structure of 1,5-S4N4C12 (32) consists of a folded eight-membered ring [d(S- -S) = 2.45 A] with the exocyclic substituents in exo,endo positions. The reaction of 32 with (Me3SiN)2S is the best route to the binary sulfur nitride S5N6 (11).42... [Pg.240]

Species 9.16 is believed to have the complex structure depicted in 9.17, which is formed by the coupling of eight-membered rings to give a cyclo-linear polymer. The excess carbon can be removed from the silico-carbo-nitride by heating with ammonia... [Pg.325]


See other pages where Nitrides eight-membered ring is mentioned: [Pg.152]    [Pg.229]    [Pg.87]    [Pg.981]    [Pg.452]    [Pg.2820]    [Pg.229]    [Pg.219]    [Pg.279]    [Pg.38]    [Pg.817]    [Pg.265]   
See also in sourсe #XX -- [ Pg.22 , Pg.281 , Pg.282 , Pg.283 , Pg.284 , Pg.285 , Pg.286 , Pg.287 , Pg.288 , Pg.289 , Pg.290 , Pg.291 ]




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