Nitrato-N-nitramines

Nitrato-N-nitramines from cyclic tert amines... 

Nitrato-N-nitramines. A soln. of startg. aziridine in methylene chloride treated with 1.25 eqs. N2O5 at -10 to —5° for 0.5 to 1 h - product. Y 70%. Reaction is only applicable with strained N-heterocyclics (aziridines, azetidines). F.e.s. P. Golding et al., Tetrahedron Letters 29, 2735-6 (1988). 

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