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Niobium derivatives, bond lengths

Tetranuclear monoadducts with asymmetrical M- O M bridges related to those of [M2OCI9] have been characterized but most structural data concern monomeric NbOCls bis adducts. In such derivatives, the metal is octahedrally surrounded with the neutral Ugands cis to each other, one being trans to the 0x0 bond, which is short (typical Nb=0 Bond Length 1.70 A). The coordination polyhedron is distorted as a result of the niobium-oxygen multiple bond (see Valence Shell Electron Pair Repulsion Model). ... [Pg.2933]

See other pages where Niobium derivatives, bond lengths is mentioned: [Pg.49]    [Pg.49]    [Pg.2055]    [Pg.589]    [Pg.77]    [Pg.144]    [Pg.1559]    [Pg.2055]   
See also in sourсe #XX -- [ Pg.1435 ]



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Bonded Derivatives

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