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Nickel self-exchange reactions

The nature of the self-exchange is still under consideration. The planned use of the copper(III)-nickel(II) and (reverse) reactions to... [Pg.279]

The Marcus analysis of the rate constants for electron transfer reactions of the [Ni((-)-(R)-Me[9]aneN3)2] couple with nickel and cobalt complexes yields a self-exchange rate constant of 1.2 x 10" The oxidations of... [Pg.32]

Cross reactions of nickel(III)- and nickel(II)-peptide complexes conform readily to Marcus theory and are thought to be outer sphere but, in contrast to the copper system, give no unique self-exchange rate. Instead values range from 550 s for [Ni(III)/(II)(H 2Aib3)] through 1.3 x... [Pg.50]


See other pages where Nickel self-exchange reactions is mentioned: [Pg.411]    [Pg.96]    [Pg.258]    [Pg.270]    [Pg.272]    [Pg.273]    [Pg.276]    [Pg.276]    [Pg.279]    [Pg.280]    [Pg.281]    [Pg.21]    [Pg.268]    [Pg.50]    [Pg.51]    [Pg.51]    [Pg.12]    [Pg.153]    [Pg.142]    [Pg.97]    [Pg.150]    [Pg.123]    [Pg.256]    [Pg.180]    [Pg.41]    [Pg.126]    [Pg.356]   
See also in sourсe #XX -- [ Pg.21 ]




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Self-exchange

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