Nickel-Dioxygen Complexes and Their Reactive Intermediates

Nickel-Dioxygen Complexes and Their Reactive Intermediates 

Ni(II)-superoxo description, with antiferromagnetic coupling between the five-coordinate Ni(II) center and the side-on superoxo radical. (PhTf Ni(II) / -02] also reacts with some external substrates including PPhs and NO to form 0=PPh3 and NOi, respectively. 

9 Kurtz, D. In Comprehendve Coordination Chemistry II, vol. 8, McCIeverty, J.A., Meyers, T.J. (Eds.), Elsevien Oxford, 

30 A copper Xp complex with an absorbance spectrum similar to that of oxyhe-mocyanin has been reported. It was prepared with H2O2 and proposed to contain a peroxo bridge between two copper centers Kitajima, N., Koda, X., Hashimo-to, S., Kitagawa, X, Moro-oko, Y. Chem Commun 1988, 151. 

31 Kitajima, N., Fujisawa, K., Fujimoto, C., Moro-oka, Y, Hashimoto, S., Kitagawa, 

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