Network formation in free-radical

The mechanistic elucidation of network formation in free-radical crosslinking polymerization and copolymerization of multivinyl compounds - a long-term controversial problem because of the complexity of the reactions involved-has been discussed on the basis of the comparison of the experimental results obtained mainly in our laboratory with F-S theory and assuming ideal network formation. 

Scheme 7 Schematic representation of the polymer network formation in free-radical copolymerization of vinyl/divinyl monomers...

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