NeNePo spectroscopy

Figure 9. Principle of NeNePo spectroscopy. The probe pulse detaches the photoelectron from the negative ion, introducing a vibrational wavepacket into the ground state of the neutral particle. Its propagation is interrogated by the probe pulse, which ionizes it to a positive ion.

E. Fragmentation of Ag202 Interrogated by NeNePo Spectroscopy Reactivity Aspects... 

To accomplish this goals, the electronic and structural properties of noble metal clusters will be addressed first. Then the attention will be paid to MD on the fly and to the simulation of signals. Furthermore, the analysis of the signals and the comparison with the experimental findings will be presented allowing for the identification of processes and conditions under which they can be observed. Finally, cluster reactivity aspects and the scope of NeNePo spectroscopy will be addressed. 

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