Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Neighboring-group participation anomerization

Acyl protection should lead, as a consequence of neighboring-group participation and the anomeric effect, exclusively to a products. This has been proved in many experiments (Table XV) with Me3SiOTf as catalyst excellent yields could be obtained in cases where all other methods essentially failed (129). It could be shown that at least some of the reactions proceed via rapid orthoester formation (129), and this intermediate then rearranges under Me3SiOTf catalysis to the desired reaction product. [Pg.58]

See other pages where Neighboring-group participation anomerization is mentioned: [Pg.3]    [Pg.3]    [Pg.445]    [Pg.530]    [Pg.80]    [Pg.81]    [Pg.89]    [Pg.91]    [Pg.98]    [Pg.109]    [Pg.165]    [Pg.175]    [Pg.229]    [Pg.47]    [Pg.47]    [Pg.140]    [Pg.188]    [Pg.270]    [Pg.7]    [Pg.193]    [Pg.244]    [Pg.292]    [Pg.383]    [Pg.390]    [Pg.414]    [Pg.449]    [Pg.299]    [Pg.33]    [Pg.13]    [Pg.24]    [Pg.32]    [Pg.39]    [Pg.387]    [Pg.702]    [Pg.37]    [Pg.42]    [Pg.71]    [Pg.71]    [Pg.98]    [Pg.99]    [Pg.101]    [Pg.113]    [Pg.132]    [Pg.571]    [Pg.45]    [Pg.115]    [Pg.132]    [Pg.160]    [Pg.200]   
See also in sourсe #XX -- [ Pg.24 ]



SEARCH



Neighbor

Neighboring group

Neighboring group participation

Neighboring group participation groups

Neighboring participation

Participating group

© 2024 chempedia.info