Negative differential resistance hidden

According to the literature [21], all reported electrochemical oscillations can be classified into four classes depending on the roles of the true electrode potential (or Helmholtz-layer potential, E). Electrochemical oscillations in which E plays no essential role and remains essentially constant are known as strictly potentiostatic (Class I) oscillations, which can be regarded as chemical oscillations containing electrochemical reactions. Electrochemical oscillations in which E is involved as an essential variable but not as the autocatalytic variable are known as S-NDR (Class II) oscillations, which arise from an S-shaped negative differential resistance (S-NDR) in the current density (/) versus E curve. Oscillations in which E is the autocatalytic variable are knovm as N-NDR (Class III) oscillations, which have an N-shaped NDR. Oscillations in which the N-NDR is obscured by a current increase from another process are knovm as hidden N-NDR (HN-NDR Class IV) oscillations. It is known that N-NDR oscillations are purely current oscillations, whereas HN-NDR oscillations occur in both current and potential. The HN-NDR oscillations can be further divided into three or four subcategories, depending on how the NDR is hidden. 

Simple Periodic Oscillations of Type II Hidden Negative Differential Resistance Oscillators... 

Cl or Br, constitutes the first experimental example where the importance of the hidden negative differential resistance for oscillatory behavior was recognized. Furthermore, the individual steps of the oscillation mechanism can easily be studied separately, allowing assignment of the essential features of the mechanism. This system therefore represents an ideal experimental model for illustrating the properties of HNDR oscillators. 

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