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N SiMe

Me3C)2Si—N —SiMe(CMe3)2 —jt (Me3C)2Si N SiMe(CMe3)2 F H ... [Pg.168]

The Lu—C cr-bonding distances range from 2.425(15) to 2.501(17) A. These distances are approximately 0.2 A shorter than the corresponding distance for a pentahapto cyclopentadienide lutetium bond as predicted from ionic radii. Coordination about the lutetium atom is a slightly distorted tetrahedron. The formal coordination number of four is extremely low for the lanthanides. The only other lanthanide complex with such a low coordination number is the 3-coordinate compound [Lu N(SiMes)2 3] 131). In both cases, the low coordination number is stabilized by the use of bulky hgands. [Pg.54]

See other pages where N SiMe is mentioned: [Pg.26]    [Pg.157]    [Pg.388]    [Pg.541]    [Pg.335]    [Pg.108]    [Pg.94]    [Pg.13]    [Pg.177]    [Pg.11]    [Pg.14]    [Pg.72]    [Pg.75]    [Pg.93]    [Pg.98]    [Pg.103]    [Pg.132]    [Pg.206]    [Pg.209]    [Pg.222]    [Pg.232]    [Pg.208]    [Pg.208]    [Pg.209]    [Pg.259]    [Pg.86]    [Pg.168]    [Pg.168]    [Pg.316]    [Pg.316]    [Pg.396]    [Pg.396]    [Pg.398]    [Pg.403]    [Pg.403]    [Pg.159]    [Pg.323]    [Pg.527]    [Pg.152]    [Pg.152]    [Pg.63]    [Pg.160]    [Pg.178]    [Pg.158]    [Pg.1087]    [Pg.93]    [Pg.102]    [Pg.275]    [Pg.54]   
See also in sourсe #XX -- [ Pg.3 , Pg.3 , Pg.284 ]

See also in sourсe #XX -- [ Pg.3 , Pg.3 , Pg.231 ]



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