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N-Nitrimines

N-Nitrosation of oximes by nitrosyl halides or nitrite esters often results in the formation of N-nitrimines, R R C=NN02, these compounds being formed by rearrangement of the initial adducts. N-Amination of oximes by chloramine or by hydroxylamine-O-sulfonic acid can result in the formation of diazo compounds (Scheme 28). The reaction, known as the Forster reaction, has been used for the preparation of aryldiazoalkanes, although better methods are usually available. Diazo ketones of the general formula (49) have also been prepared by this method from the oximes. "... [Pg.751]

Nitrosyl chloride N-Nitrimines from oximes, also with preferential replacement of bromine by chlorine... [Pg.379]

Reactions with N-nitrimines Nitrones from hydroxylamines... [Pg.411]

Carbazic acid esters N-Hydroxyureas N-Nitrimines N-Nitrosoacylamines... [Pg.622]

Azohydroperoxides O-Carbamylhydroxylamines Carbazic acid esters Hydrazoformic acid esters N-Hydroxyureas N-Nitrimines N-Nitrosoacylamines N-Nitrosocarboxylic acid amides 20 Nitrosolic acids... [Pg.595]

N-Nitrimines from imines N-Nitronitric acid esters s. 14, 359 NH N-N02... [Pg.470]

See other pages where N-Nitrimines is mentioned: [Pg.135]    [Pg.235]    [Pg.237]    [Pg.243]    [Pg.243]    [Pg.330]    [Pg.330]    [Pg.524]    [Pg.285]    [Pg.408]    [Pg.35]    [Pg.340]    [Pg.340]    [Pg.295]    [Pg.298]    [Pg.263]    [Pg.319]    [Pg.268]    [Pg.361]    [Pg.121]   


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Nitrimines

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