N-Diethyl-1,2,2-trichlorovinylamine

Reaction of 7V,A-diethyl-2,2,2-trichloroacetamide with trialkyl phosphites or triphenylphosphine to give N, N-diethyl-1,2,2-trichlorovinylamine [152-154],... 

N,N-Diethyl-1,2,2-trichlorovinylamine has been prepared by the action of trimethyl, triethyl, or triisopropyl phosphite or triphenylphosphine on N,N-diethyl-2,2,2-trichloroacetamide., These methods require a reaction temperature of 150-160° and several distillations in order to obtain a pure product. Consequently, the yields of the vinylamine are lower than by the present procedure.3... 

E pic hi orh yd rin 2-Chlorodioxene 2,A-Dinitrofluorobenzene co-Tribromo-acetophenone lodobenzene dichloride CICN, BrCN, ICn CHFCICF2N(C2Hs)2 N-Diethyl-1,2,2-trichlorovinylamine N-Chlorodiethylamine ICH2CONH2 Bromocyanoacetamide T richloroacetamides Dibromomalonamide a,fi-Dibromopropionitrile CClgCN... 

CHFCICF N(C H,) N,N-Diethyl-1,2,2-trichlorovinylamine N-Chlorodiethylamine ClsC-N=CCl (tri-chloromethy lisocyanide dichloride) Hydroximinohalides, C H,C( NOH)Cl ICH CONH Bromocyanoacetamide T richloroacetamides Dibromomalonamide a,fi-Dibromopropio-nitrile, CBr iCN), CClsCN... 

N,N-Diethyl-l,2,2-trichlorovinylamine undergoes certain reactions which involve the 1-chlorine atom. Acids and alcohols are converted to their respective chlorides. Aniline converts the vinylamine to N,N-diethyl-N -phenyl-2,2-dichloroacetamidine.3... 

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