Monoolefin-metal bonding

Monoolefin-Metal Bonding. The basis for discussion of bonding is a clear specification of structure. The structures of two monoolefin complexes, including the anion of Zeise s salt, are shown in Fig. 23-1. The fact that the plane of the olefin, and indeed the C=C axis itself, are perpendicular to... 

Figure 16-27 Two extreme formal representations of the bonding of a 1,3-butadiene group to a metal atom (a) implies that there are two more or less independent monoolefin metal interactions (b) depicts cr bonds to C-l and C-4 coupled with a monoolefin metal interaction to C-2 and C-3.

Formation of Carbon-Transition and Inner Transition Metal Bond 5.8.2.3. from Monoolefins... 

S. t) Alkyl Complexes by Insertion of Monoolefins Into tr-Alkyl-, o-Aryl-, (T-VInyl-, and tr-Acyl>Metal Bonds. 

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