Molybdenum complexes nitrosyl cyclopentadienyls

McCleverty, J.A., Seddon, D., Bailey, N.A., and Walker, N.W. (1976) The chemistry of cyclopentadienyl and related nitrosyl complexes of molybdenum, part 5. Dihalogenonitrosyl tris(pyazolyl)borato]molybdenum complexes, dieir alcoholysis, and the crystal and molecular structure of chloronitrosylisopropoxo[tris(4-chlotD-3,5-dimethylpyrazoyl)borato]molybdenum, J.Chem.Sco., Dalton Trans, 898-908. 

CYCLOPENTADIENYL)NITROSYL chromium, MOLYBDENUM, AND TUNGSTEN COMPLEXES... 

The chemistry of the dicarbonyl(7 -cyclopentadienyl)nitrosyl and the chloro-(i7 -cyclopentadienyl)dinitrosyl complexes of chromium, molybdenum, and tungsten [i.e., fT -CsHs)M(CO)j(NO)] and [(i7 -CsHs)M(NO)2Cl] has not been studied extensively, partly because of the various difficulties associated with their preparation. The procedures described below are of general applicability to all three metals and lead to the desired compounds in high yields. The carbonyl nitrosyl complexes are the synthetic precursors of the chloro nitrosyl complexes and so their preparation is described first. 

O3NSC7HS, l,2-Benzisothiazol-3(2//)-one, 1,1-dioxide, chromium and vanadium complex, 27 307, 309 O3NWC7H5, Tungsten, dicarbonyl(i -cyclopentadienyl)nitrosyl-, 28 196 03N3MoC,2H, Molybdenum,... 

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