Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Molybdenum complexes molecular orbital calculations

Oxo-transfer reactions involving molybdenum have been reviewed. The structure of trans-[Ru(0)2(py)2(0Ac)2] shows a relatively long Ru=0 bond which may be important in the role of the complex as an oxo-transfer reagent. Kinetics and mechanisms for epoxidations by [Ru(terpy)(tmen) (H20)] have been reported. Molecular orbital calculations on the formation of epoxides from Ru(IV)=0 and ethene suggest that the preferred pathway involves a nucleophilic attack on the oxo oxygen. Similar studies have been carried out on the oxidation of alcohols. The mechanism of oxidation of alcohols by [Ru OL] " where HL=[2-hydroxy-2-(2-pyridyl)ethyl]bis[2-(2-pyridyl)ethyl]amine has been investigated. The reactions are first-order in both reagents, and kinetic isotope effects on the... [Pg.35]

See other pages where Molybdenum complexes molecular orbital calculations is mentioned: [Pg.165]    [Pg.1353]    [Pg.1402]    [Pg.3429]    [Pg.3428]    [Pg.3192]    [Pg.3241]    [Pg.706]    [Pg.4]    [Pg.167]    [Pg.210]    [Pg.8]    [Pg.29]    [Pg.2807]    [Pg.55]    [Pg.441]    [Pg.29]    [Pg.44]   
See also in sourсe #XX -- [ Pg.118 , Pg.119 , Pg.120 , Pg.121 , Pg.122 , Pg.123 , Pg.124 , Pg.125 , Pg.126 , Pg.127 ]

See also in sourсe #XX -- [ Pg.118 , Pg.119 , Pg.120 , Pg.121 , Pg.122 , Pg.123 , Pg.124 , Pg.125 , Pg.126 , Pg.127 ]



SEARCH



Calculations orbital

Molecular calculated

Molecular calculations

Molecular complex

Molecular complex calculations

Molecular orbital calculations

Molecular orbitals calculating

Molecular-orbital calculations complexes

Orbit complex

Orbital complex

Orbitals calculation

Orbitals complexes

© 2024 chempedia.info