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Rhomboidal cluster compounds, molybdenum

The preceding three reduced molybdenum clusters indicate that rhomboidal cluster units are common among this kind of oxide, and the Mo-Mo distances in the cluster units are dependent on CVE assignable to the Mo4 units. MO calculations on Mo4 molecular cluster compounds containing 10 CVE and 8 CVE have shown that the 8-electron clusters distort from a second-order Jahn-Teller effect (116). Such a distortion has been observed in the 8-electron W4(OEt)16 (117). [Pg.81]


See other pages where Rhomboidal cluster compounds, molybdenum is mentioned: [Pg.263]    [Pg.262]    [Pg.81]    [Pg.81]   
See also in sourсe #XX -- [ Pg.75 , Pg.76 , Pg.77 , Pg.78 , Pg.79 , Pg.80 , Pg.81 ]

See also in sourсe #XX -- [ Pg.75 , Pg.76 , Pg.77 , Pg.78 , Pg.79 , Pg.80 , Pg.81 ]




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Molybdenum clusters

Molybdenum compounds

Rhomboid

Rhomboidal Clusters

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