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Molybdenum bond dissociation energies

Application of the anharmonic diatomic approximation as discussed for the Re2Xg" ions was also employed to estimate a bond dissociation energy for Mo2C18 (243). Employing the w, and Xi i values obtained by Clark and Franks (47) as data for the Birge-Sponer extrapolation led to a calculated energy of 172 20, 190 25, and 127 15 kcal mole"1 for the molybdenum-... [Pg.271]

Compounds containing Mo—Mo, W—W, or Related Bonds.— Some tentative spectral evidence has been obtained for the formation of Mo2 dimers when isolated molybdenum atoms are allowed to diffuse through an Ar matrix.273 The kinetics of the formation and dissociation of W2 and WRe adatom species have been studied by field ion microscopy and their dissociation energies estimated as 30 5 and 14 + 2 kJ mol-1, respectively, at ca. 400K.395... [Pg.125]

See other pages where Molybdenum bond dissociation energies is mentioned: [Pg.49]    [Pg.1301]    [Pg.271]    [Pg.272]    [Pg.1572]    [Pg.40]    [Pg.3140]    [Pg.289]    [Pg.74]    [Pg.196]    [Pg.55]    [Pg.8]    [Pg.98]    [Pg.258]    [Pg.116]    [Pg.244]    [Pg.319]    [Pg.9]    [Pg.4]    [Pg.51]    [Pg.153]   
See also in sourсe #XX -- [ Pg.4 , Pg.48 ]

See also in sourсe #XX -- [ Pg.4 , Pg.48 ]



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