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Molecular symmetry group, reaction paths

By molecular reactions, we mean that group of concerted reactions which are neither ionic, nor radical, and which have no mechanism (Rhoads, 1963). The basic idea is that those reaction paths are favored in which orbital symmetry is conserved. Their work quickly provoked contributions from theoreticians and experimentalists alike. Fukui (1965, 1966 Fukui and Fujimoto, 1965, 1966), for example, must be credited with extending their ideas to include heterolytic and homolytic reactions. All of this work will be considered in detail. [Pg.202]

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Group path

Group symmetry

Molecular symmetry

Reaction molecular

Reaction path

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