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Molecular orbital theory Carbonyl ligands

We apply molecular orbital theory to octahedral coordination complexes just as we did for the simple metal carbonyl in Section 8.2. We begin by constructing the cr MOs from the valence d, s, and p orbitals of the central metal atom and the six ligand orbitals that point along the metal-ligand bond directions in an octahedral complex. In the case of the Cr complexes we use as examples, the relevant... [Pg.349]


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