Molecular orbital diagram, octahedral transition metal

FIGURE 18.9 Interpretation of M—charge transfer absorption in an octahedral complex using a modified molecular orbital diagram.The transitions are from e or t2g orbitals on the metal to orbitals on the ligands. 

Figure 19.14 Molecular orbital diagram for an octahedral complex of a first series transition metal (only a interactions are considered in this simplified diagram).

Figure 5 Schematic presentation of a molecular orbital diagram for an octahedral d6 metal complex involving 2,2 -bipyridyl-type ligands, in which various possible transitions are indicated.

Figure 1.8 Molecular orbital diagram for an octahedral d-block metal complex ML6. The vertical arrows indicate different types of electron transition that may be brought about by photon absorption...

Figure 7.5 A molecular orbital diagram for octahedrally coordinated transition metal ions...

Fig. 6. Molecular orbital diagram for an octahedral transition metal complex MLe illustrating different types of electronic transitions based on localized orbital configurations (MC, metal-centered LC, ligand-centered MLCT, metal-to-ligand charge transfer LMCT, ligand-to-metal charge transfer). Adapted from Ref. (1).

Fig. 11.53 Simplified molecular orbital diagram for an octahedral ML complex showing possible metal-to-ligand charge transfer (MLCT) transitions when both the t-ig and orbitals are occupied and the ligands have empty ir orbitals.

Molecular orbital diagrams for octahedral complexes, A. The mixing diagram for six equivalent ligands that bond to a transition metal possessing hybrid orbitals. B. The MO diagram for six equivalent ligands that bond to an unhybridized metal. 

Figure 1.10. Molecular orbital diagram for an octahedral transition metal complex.

Fig. 1. Schematic orbital energy diagram representing various types of electronic transitions in octahedral complexes. A line connects an atomic orbital to that molecular orbital in which it has the greatest participation. 1 metal centered (MC) transitions 2 ligand centered (LC) transitions 3a ligand-to-metal charge transfer (LMCT) transitions 3b metal-to-ligand charge transfer (MLCT) transitions...

Figure 2.5 Schematic molecular orbital energy level diagram for a transition metal coordination cluster, [ML6]. (a) Energy levels of atomic orbitals of the free cation, M (b) energy levels for the six ligands, L, before bonding (c) molecular orbital energy levels for the octahedral [ML6] cluster.

Fig. 20-39. The molecular orbital energy-level diagram, qualitative, for an octahedral complex between a metal ion of the first transition series and six ligands that do not possess...

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