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Molecular linchpins

Molecular Linchpins in Sequential Cross-Coupling Approaches to Polyunsaturated Natural Products 40... [Pg.37]

Hexatriene-1,6-Distannanes as Molecular Linchpins in Natural Product Synthesis 42... [Pg.37]

HEXATRIENE-1,6-DISTANNANES AS MOLECULAR LINCHPINS IN SEQUENTIAL CROSS-COUPLING APPROACHES TO POLYUNSATURATED NATURAL PRODUCTS... [Pg.40]

A total of three 1, co-bis(trialkylstannylated) monoene and diene building blocks was known in the mid-1990s (Fig. 4). At that time we began to explore the synthetic chemistry of polyunsaturated y-alkylidenebutenolides. We were intrigued to learn that the mentioned distannanes acted as molecular linchpins under Stille-coupling conditions in the Nicolaou, Danishefsky, and Mullen groups. These transformations are shown in Schemes 1-3. [Pg.40]

See other pages where Molecular linchpins is mentioned: [Pg.182]    [Pg.586]    [Pg.464]    [Pg.130]    [Pg.1123]    [Pg.5]   
See also in sourсe #XX -- [ Pg.40 ]



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