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Molecular Clusters of Dimetalated

Molecular Clusters of Dimetalated Primary Phosphanes and Arsanes Matthias Driess... [Pg.651]

MOLECULAR CLUSTERS OF DIMETALATED PRIMARY PHOSPHANES AND ARSANES... [Pg.235]

M. Driess, Molecular clusters of dimetallated primary phosphanes—, Adv. Inorg. Chem., 50, 235,... [Pg.700]

Reviews covering the chemistry of group 2 metal complexes with phosphorus-stabilized carbanions,279 and of molecular clusters of magnesium dimetallated primary phosphanes, are available.2 u Magnesium phosphanes remain rare compounds.281 Lithiation of bromide 98 with BuLi in the presence of tmeda in pentane produces a lithium phosphine dimer subsequent treatment with MgCl2 in EtzO gives the phosphane 99 in 69% overall yield (Equation (19)). The centrosymmetric 99 has Mg-C = 2.217 A Mg-P = 2.77 A (av.).282... [Pg.110]

See other pages where Molecular Clusters of Dimetalated is mentioned: [Pg.476]    [Pg.483]    [Pg.287]    [Pg.476]    [Pg.483]    [Pg.287]    [Pg.39]    [Pg.236]    [Pg.404]    [Pg.404]    [Pg.9]    [Pg.236]    [Pg.341]    [Pg.240]    [Pg.296]    [Pg.187]    [Pg.240]    [Pg.142]   


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Dimetallation

Dimetallic

Molecular Clusters of Dimetalated Primary Phosphanes and Arsanes

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