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Model at the various

The authors assumed a model of the various interfaces as shown in Figure 2.82(b). The Si was the underlying substrate on which the copper electrode was deposited. Such a structure will give rise to the reflections as shown, each one characterised by a wavevector transfer for both sides of the interface at which the reflection occurs. By applying the Fresnel equations to the reflections in the model in Figure 2.82(b), the reflectivity R can be derived. [Pg.158]

The relevant parameters of the model for the various end-members adopted by Ottonello et al. (1996) are listed in table 5.25. The to limit is the most critical parameter for the estimation of macroscopic thermodynamic functions. Values of to at Ai = 0 (center of the Brillouin zone) based on infrared spectra may be reduced to ai K = [Pg.259]

The Born coefficients of the HKF model for the various organic species are simply related to their standard partial molal entropies at 25 °C and 1 bar through the effective charge (Shock et al., 1989). [Pg.565]

The differences in the rate of adsorption are primarily attributable to the differences in the equilibrium capacity at the various pHs, and the pore diffusion model simulated our data satisfactorily. [Pg.516]

Whereas chain models still allow for a relatively unified treatment of various aspects of amphiphilic systems, such as their bulk phase behavior and the properties of monolayers and bilayers, this is no longer true for the even more idealized models at the next level of coarse graining. These usually have to be adapted very specifically to the problem one wishes to study. [Pg.655]

Hiemstra, T., De Wit, J.C.M., and Van Riemsdijk, W.H., Multisite proton adsorption modeling at the solid/solution interface of (hydr)oxides A new approach. II. Application to various important (hydr)oxides, J. Colloid Interface Sci., 133, 105, 1989. [Pg.120]

Since in most cases detailed information on the characteristics of the sediments along the river is missing, it is hardly justified to attempt to calculate vsedex from a mechanistic model of the various processes involved. However, there are situations in which we should at least remember that vsedex may depend on the exposure history of the river sediments. In Section 24.3 we will discuss such a case the pollution of the River Rhine by a pesticide after a fire in a storehouse. In this and similar cases, [Pg.1116]

Hiemstra, T., J. C. M. de Wit, and W. O. van Riemsdijk (1989), "Multisite Proton Adsorption Modeling at the Solid/Solution Interface of (Hydr)Oxides, II. Application to Various Important (Hydr)Oxides", J. Colloid Interf. Sci. 133, 105-117. [Pg.404]

Although a treatment like this can be considered straightforward and even trivial, very few workers have applied similar models for extracting maximum information from their data. We shall now treat a slightly more complicated model and look at the various special cases that occur. [Pg.109]

In terms of selectivity and reduced sensitivity to initial moisture and inoculum, the results indicate that shorter treatment times are preferred, especially if moisture is either not controlled or poorly controlled. The regression models were next used to generate topographic plots of AX, AG, and AX/AG at the various combinations of inoculum and moisture. [Pg.87]

Proton nuclei located at different positions within the small molecules and amino adds that were investigated exhibit similar degrees of spin-probe accessibility as shown by the similar values of slope d(l/Ti)/dC for these protons in the presence of the neutral spin-probe IV. This experimental observation is consistent with the theoretical estimation of spin-probe accessibility as studied by computer-assisted molecular modeling of the various amino acid/spin-probe encounter complexes in our study. [Pg.154]


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See also in sourсe #XX -- [ Pg.470 ]

See also in sourсe #XX -- [ Pg.470 ]




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