MOCNs

MoNC framework to MoCN with formal reduction of the metal center (from 18-electron) Mo to (16-electron) Mo"... 

HIGH-NUCLEARITY CARBONYL CLUSTERS OS6(CO)i7(MeCN) or 0s6(C0)i6(MoCN)2... 

Amin (4-Brom-phenyl)-methyl-nitroso- XI/1, 981 HarnstofT l-(3-Brom-pheny])- E4, 363 (MOCN + Amin)... 

Some of these techniques may be applied to coat a solid layer on monoliths, provided suitable reactions and appropriate reaction conditions arc chosen. Mocne ct al. [106,107] described the coating of a SiC layer on a microporous active carbon surface using the CVD or CVI techniques. Their results can easily be translated to monolithic catalyst support synthesis. 

C. Apostolidis, H. Bokelund, M. Ougier and A. Mocns, Inorgan. Chim. Acta 140 253 (1987). 

Two types of strategy are used to obtain enantiopure MOCNs. The one employed most often consists of introducing the chiral information into the assembly ligand of the metallic ion network. The molecules most frequently used for this are binaphthol derivatives, tartrate ions, polypyridines substituted with chiral groups and amino acids. It is also possible to prefabricate a chiral building block of known configuration, the self-assembly of which leads to the desired MOCNs. 

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