Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Mo-X bonds

The broken bonds (boldface=dissociated BDEs (boldface = recommended data reference in parentheses) Methods (reference in  [Pg.734]

When applying these methods to the study of molybdenum complexes Voityuk and Rosch [25, 41] found that the use of the AMI core-repulsion function (Eq. 5-6) led to some systematic deviations for some Mo—X bond lengths. To address these problems, important changes to the core-repulsion function were made by the introduction of bond-specific parameters (omo-x and 8 io-x, Eq. 5-9) [22, 25], The idea of using bond-specific core repulsion parameters is not new, since the AMI parameterisation of boron used bond-specific Gaussian functions to improve the final results [42],... [Pg.111]

Intermediate 1 arising from the reductive cleavage of two Mo-S or of two Mo-X bonds, namely cw-[Mo2Cp2(CO)2(p-SMe)2], is detected by cyclic voltammetry and converts to its stable trans isomer on the electrolysis time-scale (Scheme 3). ... [Pg.38]

See other pages where Mo-X bonds is mentioned: [Pg.578]    [Pg.1792]    [Pg.458]    [Pg.578]    [Pg.21]    [Pg.21]    [Pg.734]    [Pg.734]    [Pg.734]    [Pg.736]    [Pg.738]    [Pg.740]    [Pg.742]    [Pg.744]    [Pg.746]    [Pg.746]    [Pg.748]    [Pg.750]    [Pg.751]    [Pg.751]    [Pg.1791]    [Pg.346]    [Pg.4049]    [Pg.5491]    [Pg.445]    [Pg.37]    [Pg.41]    [Pg.193]   


SEARCH



Bonding MO

X-bonds

© 2024 chempedia.info