Mixed-metal carbonyl clusters

The limited magnetic measurements of very mixed -metal clusters are summarized in Table XIII. The magnetic behavior of some anti-ferromagnetic very mixed -metal carbonyl clusters (Fig. 82) has been studied by Pasynskii and eo-workers. Temperature dependences of the magnetic susceptibilities of Cr2Co(/t3-S)3(/i-SBu )(CO)2() -C3H4R)2l (R = H. Me) have been determined us-... 

The reaction with [Mn(CO)5]2 or [Co(CO)4]2 also led to mixed-metal clusters.962,963 Osmium-palladium mixed-metal carbonyl clusters were made using the unsaturated cluster [Os3(CO)io(/r-H)2] and the carbido cluster [Os5(/U5-C)(CO)15].964 970 Treatment of [Os3(CO)10Gu-H)2] with [Pd2(/u-dppm)2Cl2] afforded the novel high-nuclearity osmium-palladium mixed-metal carbonyl clusters [Os5Pd6(CO)13( -CO)5(/u-H)2(/u-dppm)2], [Os5Pd6(CO)13(//-CO)6(/u-dppm)2], and... 

Waterman, Susan M., Lucas, Nigel T., and Humphrey, Mark G., Very-Mixed -Metal Carbonyl Clusters. 46 47... 

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