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Miscellaneous 5- substituted

Structure and Stereochemistry (it is self-subdivided into Theoretical Aspects, Stereochemical Aspects, Betaines and Other Unusual Structures, Miscellaneous Substituted Heterocycles). [Pg.148]

Miscellaneous Substitution Reactions.—A reaction cycle has been described for the synthesis of non-geminal bromofluorocyclotriphosphazenes NaPaFa Br ... [Pg.269]

This section deals with the generation and reactivity of carbanions, carbenium ions and carbon radicals adjacent to the thiophene ring. A few miscellaneous substituted alkyl groups will also be covered. [Pg.562]

Cyclic systems Miscellaneous substituted Ca-acid derivatives... [Pg.69]

Miscellaneous substituted Cs-acid derivatives 3.1.7.1 p-Heteroatom substituted derivatives... [Pg.129]

Miscellaneous Substitution Reactions (mostly Nucleophilic).— The 5-halogen-substituent in isothiazoles is readily replaced by nucleophilic substitution with alkoxy- or hydroxy-groups this provides a route to 5-alkoxy-3-methyl-4-nitroisothiazoles and 5-hydroxy-4-nitroisothiazoles. 4,5-Dihromo-3-methylisothiazole affords the 5-butoxy-compound on treatment with sodium butoxide in butanol, and the 5-hydroxy-compound with methanolic sodium hydroxide, but fails to react with sodium methoxide. ... [Pg.570]

Miscellaneous Substitutions.— The enhanced reactivity of the 2-methyl group in thiazole is illustrated by the hydroxyalkylation of 2,4-dimcthyl-thiazole to the alcohols (62), on successive treatment with lithium amide in liquid ammonia, and with a carbonyl compound the products are readily dehydrated to the ethylenes (63). ... [Pg.599]

Other miscellaneous substitutions include the attempted bromination, acetoxymercuration, tritylation, idoination, lithiation, Vilsmeier, and diazocoupling reactions on the l,6-dioxa-6aA -thiapentalene system (88) electrophilic reaction occurs at positions 3 (and 4). The few attempts at electrophilic substitution in arsabenzene have been reviewed. ... [Pg.286]

See other pages where Miscellaneous 5- substituted is mentioned: [Pg.401]    [Pg.487]    [Pg.207]    [Pg.961]    [Pg.74]    [Pg.51]    [Pg.55]    [Pg.57]    [Pg.295]    [Pg.215]    [Pg.287]    [Pg.38]    [Pg.505]    [Pg.530]    [Pg.173]    [Pg.189]    [Pg.173]    [Pg.189]    [Pg.150]    [Pg.269]    [Pg.278]    [Pg.51]    [Pg.55]    [Pg.57]    [Pg.6]    [Pg.163]    [Pg.207]    [Pg.7]    [Pg.149]    [Pg.173]    [Pg.189]    [Pg.208]    [Pg.207]    [Pg.282]    [Pg.383]    [Pg.774]   
See also in sourсe #XX -- [ Pg.518 ]



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Miscellaneous substituted piperidines

Nucleophilic substitution miscellaneous compounds

Substituted and miscellaneous enamines

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