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Mingos cluster valence electron count schemes

In both [Fe4X4(N0)4](X = S or Se) and [Fe4S2(NO)4(NCMe3)2] the total valence electron count is 60. This is the number characteristic of tetrahedral tetranuclear metal clusters, such as [Ir4(CO)12], in the Wade and Mingos skeletal-electron counting schemes (76, 77) and, furthermore, each iron atom in these clusters obeys the 18-electron rule, provided that it forms single Fe-Fe bonds to each of the other iron atoms in the tetrahedron. [Pg.368]


See other pages where Mingos cluster valence electron count schemes is mentioned: [Pg.1746]    [Pg.1745]    [Pg.306]    [Pg.236]    [Pg.23]    [Pg.227]   


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Cluster valence electron

Counting scheme

Electron clusters

Electron counting cluster

Electron counts

Electron-counting schemes

Electronic counting

Mingos

Valence electron

Valence electron count

Valence electrons Valency

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