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MILAS Olefin Hydroxylation

Interestingly, the first examples of catalytic oxygen transfer involved the so-called Milas reagents,4 formed by mixing heterogeneous metal oxide catalysts with a solution of hydrogen peroxide in tert-butanol. These reagents were used for the vicinal hydroxylation of olefins (reaction 10). [Pg.36]

Oxidation systems based on osmium have been extensively researched for the hydroxylation of olefins. Hydrogen peroxide/Os04 (Milas reagent) will hydro-... [Pg.102]

Milas hydroxylation of olefins. Formation of cw-glycols by reaction of alkenes with hydrogen peroxide and either a catalytic amount of osmium, vanadium, or chromium oxide or UV light. [Pg.849]

The catalytic hydroxylation of olefins with was first reported by Milas in 1936 [3, 4] and studied in more detail by Mugdan and Young a few years later... [Pg.21]

See other pages where MILAS Olefin Hydroxylation is mentioned: [Pg.246]    [Pg.365]    [Pg.246]    [Pg.246]    [Pg.365]    [Pg.246]    [Pg.134]    [Pg.1948]    [Pg.376]    [Pg.189]   
See also in sourсe #XX -- [ Pg.246 ]

See also in sourсe #XX -- [ Pg.263 ]

See also in sourсe #XX -- [ Pg.246 ]



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Olefins hydroxylation

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