Micellar-mediated bimolecular reactions

The reaction mechanism for such a micellar-mediated bimolecular reaction may be expressed by Scheme 3.4, which can lead to Equation 3.5. 

Almost all the micellar-mediated bimolecular reactions so far reported involve parallel reaction steps that constitute reactions occurring simultaneously in both aqueous phase and micellar pseudophase as expressed in Scheme 3.8. As described earlier, there are only a few reports that show an apparent failure of bimolecular reactions to obey the reaction in Scheme 3.8. However, this failure is attributed to various factors, including the possibility of cross-interface reaction. ... 

For the micellar-mediated bimolecular reactions that follow the reaction scheme as shown by Schane 3.8, if we assume that the changes in Kg and Kr due to increase in at a constant [ionic surfactant] follow empirical equa-... 

Within the domain of PP model, the general reaction scheme for a bimolecular reaction between reactants, S and R, in the presence of micelle, D , is shown in Scheme 3.8 (Chapter 3). Almost all the kinetic data, obtained for micellar-mediated bimolecular reactions, have been discnssed in terms of PP or extended... 

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