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Methylthio acetic acid

More conveniently, 2-(methylthio)alkanoic esters are prepared from 2-acetylalkanoates (eq 2)] MeSSMe cannot replace MeSS02Me as the sulfenylating agent in this transformation. Advantages of these methods over others such as sulfenylation of an alkanoic acid and its ester or alkylation of (methylthio)acetic acid are (1) simplicity of the procedure (2) efficiency and convenience of using inexpensive base (EtONa) and EtOH as solvent with high product yields and (3) no bissulfenylation. Moreover, the latter... [Pg.374]

Obtained by acylation of 2,6-di-tert-butylphe-nol with 2-(methylthio)acetic acid and the intermediate oxidized with m-CPBA [5604],... [Pg.1555]

See other pages where Methylthio acetic acid is mentioned: [Pg.134]    [Pg.174]    [Pg.187]    [Pg.131]    [Pg.498]    [Pg.499]    [Pg.1238]    [Pg.490]    [Pg.491]    [Pg.1199]    [Pg.1243]    [Pg.286]    [Pg.477]    [Pg.1134]    [Pg.541]    [Pg.542]    [Pg.973]    [Pg.1278]    [Pg.529]    [Pg.934]    [Pg.540]    [Pg.970]    [Pg.490]    [Pg.491]    [Pg.1197]    [Pg.27]   
See also in sourсe #XX -- [ Pg.159 ]



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5- -2-methylthio

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