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Methyl fluoroformate

Methyl fluoroform, t291 Methyl 2-furancarboxylate, m253 5-Methylfurfural, m251 a-Methyl-D-glucopyranoside, m256... [Pg.301]

The elusive ionic and neutral fluorohydroxymethylenes (FCOH) are accessible in the gas phase140. The ion 53, produced by CH20 loss from methyl fluoroformate, FCOOCH3, under El conditions was differentiated from its isomer 54 by means of CID analysis. Ab initio MO calculations (MP2/6-31G //MP2/6-31G + ZPVE) indicate that 53 is more stable than 54 by 13.7 kcalmof1 and that the spontaneous rearrangement of 54 to 53 is... [Pg.217]

Methyl fluoroformate, obtained by the action of thallium fluoride on methyl chloroformate, is a liquid boiling at 40° C. Density i-o6 at 33° C. [Pg.100]

CH3F (trace). Pyrolysis of sodium trifluoroacetate alone yields trifluoro-acetyl fluoride and trifluoroacetic anhydride pyrolysis of sodium trifluoroacetate in the presence of sodium hydroxide, however, does appear to give difluorocarbene since tetrafluoroethylene is produced in at least 32% yield. Data from kinetic studies on hydrogen atom abstraction by Me and CFa (generated by photolysis of acetone and hexafluoroacetone, respectively) from methyl trifluoroacetate and methyl fluoroformate have been presented and discussed. ... [Pg.136]

See other pages where Methyl fluoroformate is mentioned: [Pg.97]    [Pg.691]    [Pg.410]    [Pg.1411]    [Pg.1357]    [Pg.410]    [Pg.671]    [Pg.711]    [Pg.1578]    [Pg.674]    [Pg.257]    [Pg.261]    [Pg.659]    [Pg.1569]    [Pg.670]    [Pg.710]    [Pg.1578]    [Pg.1411]    [Pg.880]    [Pg.1606]   
See also in sourсe #XX -- [ Pg.131 ]

See also in sourсe #XX -- [ Pg.97 ]

See also in sourсe #XX -- [ Pg.691 ]



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Fluoroformates

Fluoroformic acid, methyl ester

Methyl fluoroformate, reaction

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