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Methyl 2,6-difluorobenzoate

In 1998, Ube Industries, Ltd. discovered that pentafluorobenzoates, such as methyl pentafluorobenzoate (62), can be used as additives in small quantities [92], Also, in 1999, Toyota Central R D Labs found that fluorinated benzoates, such as methyl 2,6-difluorobenzoate (63), can be used as additives in small quantities [93], and in 2002, Ube Industries, Ltd. found that pentafluorophenol compounds, such as pentafluorophenyl methanesulfonate (64) and methyl pentafluorophenyl carbonate (65), can be used as additives in small quantities [94]. [Pg.181]

Interestingly, the photolysis of methyl 3-azido-2.6-difluorobenzoate (61) in diethylamine yields, in addition to the two expected 3//-azepines 62 and 63, a third azepine 64 formed by nucleophilic displacement of allylic fluorine from the 3-position by diethylamine.188 Displacement of allylic halogen from haloazepines has been noted previously.177... [Pg.151]


See other pages where Methyl 2,6-difluorobenzoate is mentioned: [Pg.987]    [Pg.1016]    [Pg.987]    [Pg.1016]    [Pg.245]    [Pg.258]    [Pg.22]   
See also in sourсe #XX -- [ Pg.181 ]




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Difluorobenzoate

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