Trifluoroiodo methane

Table 9 Trifluoromethyl Ketones Synthesized by Reacting Peptide Aldehydes with Trifluoroiodo-methane/Zinc 31l...

Deprotonation of some molybdenum-carbyne complexes affords vinylidene derivatives suitable reagents are aryldiazonium salts, trifluoroiodo-methane 34), or n-butyllithium (55) ... 

Perfluoroalkylation can also be carried out using bromotrifluoromethane and trifluoroiodo-methane in the presence of tris(diethylamino)phosphane with chlorotriethylgermane, e.g. formation of 5. ... 

Trifluoronitrosomethane may be obtained from photolysis of a mixture of trifluoroiodo-methane and nitric oxide [275, 276] or from pyrolysis of trifluoroacetyl nitrite [277, 278] (Figure 8.108). 

Bromoandrost-16-ene adds hydrogen bromide under irradiation to give 16, 17j8-dibromoandrostane. A photochemical addition of trifluoroiodo-methane on to a A -olefin is mentioned on p. 258. 

Glacial acetic acid is a suitable solvent for use with silver acetate and CC14 or, up to 150°, nitrobenzene for use with silver trifluoroacetate. The Hunsdiecker reaction (see p. 1005) may intervene as competing reaction 377 trifluoroiodo-methane, for example, may be formed when iodine, silver trifluoroacetate, and nitrobenzene are heated in the absence of a substance that can be iodinated CF3COOAg + I2 ------------------------ CF3I + Agl + C02... 

Related Reagents. trifluoromethylcopper(I) trifluoroiodo-methane (trifluoromethyl)dibenzothiophenium triflate and tetrafluoroborate (trifluoromethyl)dibenzoselenophenium triflate and tetrafluoroborate. 

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